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Place the silicone chocolate mold on a small baking sheet. Set aside.
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Place the chocolate melting wafers in a microwave safe bowl. Heat in the microwave, stirring every 30 seconds until melted.
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Transfer the melted chocolate into the silicone mold, dividing it evenly between each cup. Aim to fill the cups about halfway full. Gently swirl the chocolate in the molds so that the sides are covered.
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Place the baking sheet with the mold into the refrigerator. Chill until the chocolate is set, about 15 minutes.
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In a small saucepan, combine the water and the caramel bits. Heat over medium heat, stirring occasionally, until melted. Transfer the caramel to a heat safe bowl and let cool briefly. The caramel should be warm, but not too hot to handle.
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Remove the chocolate filled mold from the refrigerator. Transfer the caramel to a piping bag and pipe an even layer on top of the chocolate.
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Gently press the pecans into the caramel, covering it completely. Place the baking tray with the silicone mold back into the refrigerator to set, about 15 minutes.