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Preheat the oven to 350 F. Spray the brownie bowl pan with cooking spray. Set aside.
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In a large bowl, whisk together the sugar, flour, cornstarch, cocoa powder, baking powder, espresso powder, salt, and baking soda.
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Add the eggs, oil, and vanilla and beat until smooth.
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Gradually add the water, beating until smooth.
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Stir in the mini chocolate chips.
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Divide the batter between the six wells in the brownie bowl pan. Tap the pan on the counter a couple times to remove air bubbles.
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Bake the cakes for 25-28 minutes or until the cakes spring back when lightly touched.
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Cool the cakes for 10 minutes in the pan before transferring to a wire rack to cool completely. The easiest way to remove the cakes from the pan is to place a wire rack on top of the pan and then flip the pan over.